- (1999) Radio commercial: Taco Bell
- (1999) TV commercial: Taco Bell
- (1999) TV commercial: Taco Bell (Speed parody)
- (2000) Radio commercial: TechieGold goldfish (voiceover)
- (1980s) TV commercials: Maxwell House Instant Coffee
- (2003) TV commercial: Dunkin' Donuts coffee
- (1975-78) TV commercials: Chrysler's Cordoba sedan. Montalban's suave delivery and emphasis on the car's interior option of "fine Corinthian leather" became a popular culture catchphrase for several years during and after the ad campaign.
- (1986) Recorded a public service announcement celebrating the United States' generosity and hospitality to him as a foreign-born actor, honoring the 100th anniversary of the Statue of Liberty.
- (1961) Unsold pilot: He starred in a pilot for a proposed CBS dramatic series called "Baron Gus" about a European nobleman who traveled around the United States in a motor home researching articles about the country for his own nation's newspapers.
- (1968) Unsold pilot: He starred in a 15-minute pilot for a proposed series to be called "Joaquin Murietta", in which he played a bandit in Spanish California with a heart of gold. NBC did not pick up the series but the concept was recast and offered as a two-hour-long pilot in 1969.
- (1973) Stage: Appeared (as "Don Juan") in "Don Juan in Hell" on Broadway. Comedy (revival). Written by George Bernard Shaw. Directed by John Houseman. Palace Theatre: 15 Jan 1973-4 Feb 1973 (24 performances). Cast: Paul Henreid (as "Commander"), Agnes Moorehead (as "Dona Ana"), Edward Mulhare (as "The Devil"). Produced by Lee Orgel and William J. Griffiths.
- (1957) Stage: Appeared (as "Koli") in "Jamaica" on Broadway. Musical. Book by E.Y. Harburg (also lyrics) and Fred Saidy. Music by Harold Arlen. Musical Direction / Xontinuity / Vocals by Lehman Engel. Dance Music / Additional Vocals by Peter Matz. Music orchestrated by Philip J. Lang. Choreographed by Jack Cole. Production Stage Manager: Neil Hartley. Stage Manager: Charles Blackwell. Directed by Robert Lewis. Imperial Theatre: 31 Oct 1957-11 Apr 1959 (555 performances). Cast: Lena Horne (as "Savannah"), Adelaide Hall, Josephine Premice, Joe Adams, Alvin Ailey, Ethel Ayler, Adelaide Boatner, George Boreland, Hugh Bryant, Herbert Coleman, Jayne Craddock, Ossie Davis (as "Cicero"), Hugh Dilworth, Norma Donaldson, Patricia Dunn, Doris Galiber, Frank Glass, Harold Gordon, Lavinia Hamilton, Sandra Hinton, Nat Horne, Albert Johnson, Chailendra Jones, Cristyne Lawson, Tony Martinez, Audrey Mason, Jim McMillan, Charles Moore, Sally Neal, Pearl Reynolds, Erik Rhodes (as "The Governor"), Allen Richards, Augustine Rios, Alan Shayne, Christine Spencer, Carolyn Stanford, Claude Thompson, Roy Thompson, Ben Vargas, Jacqueline Walcott, James E. Wall, Billy Wilson, Barbara Wright, Michael Wright. Understudies: Ethel Ayler (as "Savannah"), Charles Blackwell (as "Joe Nashua"), Adelaide Boatner (as "Grandma Obeah"), Hugh Bryant (as "Koli, Radio Announcer"), Virginia Capers (as "Grandma Obeah"), Herbert Coleman (as "Quico"), Alan Shayne (as "Koli, The Governor"), Roy Thompson (as "Joe Nashua"), Jacqueline Walcott (as "Ginger"), James E. Wall (as "Cicero"). Produced by David Merrick. NOTE: Montalban was nominated for a Tony Award as Best Actor.
- (1955) Stage: Appeared (as "Chico"; Broadway debut) in "Seventh Heaven" on Broadway. Musical. Music by Victor Young. Lyrics by Stella Unger. Material by Victor Wolfson and Stella Unger. Based on the play by Austin Strong. Musical Direction by Max Meth. Music orchestrated by David Terry. Choral direction by Crane Calder. Choreographed by Peter Gennaro. Scenic Design by Marcel Vertès. Uncredited show doctoring by Jerome Robbins. Directed by John C. Wilson. ANTA Playhouse: 26 May 1955-2 Jul 1955 (44 performances). Cast: Gloria DeHaven (as "Diane"), Kurt Kasznar (as "Boule"), Winifred Ainslee, Bea Arthur (as "Mme. Suze"), Lee Becker, Malcolm Lee Beggs, Walter Brandin, George Burles, William Carson, John Carter, Robert Clary (as "Fleegle, The Rat"), David Collyer, Philip Cook, Dominic Cortese, Victor Duntiere, Bonnie Evans, Joe Flynn (as "Baker Boy" / "Second American Soldier" / "Singer"), William Guske, Edmund Hall, Patricia Hammerlee, Gwen Harmon, Barclay Hodges, Ferdi Hoffman, Leo Kayworth, Nancy Lynch, Joy Marlene, Scott Merrill, Alexandra Moss, Ralph Quist, Gerrianne Raphael, Chita Rivera (as "Fifi"), Raymond St. Jacques (as "First Senegalese" / "First French Soldier" / "Singer"), Philip Salem, Jeanne Schlegel, Betty Jane Seagle, Helena Seroy, Barbara Stabile, Nanette Vezina, Rebecca Vorno, James E. Wall, Ralph Wayne, Jimmy White. Produced by Gant Gaither and William Bacher.
- (Summer 1976) He acted in Samson Raphaelson's play, "Accent on Youth", in a Kenley Players production at the Packard Music Hall Theatre in Warren; the Veterans Memorial Theatre in Columbus and Memorial Hall in Dayton, Ohio. John Kenley was artistic director.
- (9/25/47) Radio: Appeared in a "Family Theater of the Air" broadcast of "Blue Memorandum".
- (2/12/51) Radio: Appeared (as "Roderigues") in a "Lux Radio Theatre" broadcast of "Battleground".
- (9/8/52) Radio: Appeared in a "Radio Theater" broadcast of "Two Weeks with Love".
- (1983) TV commercial: Chrysler New Yorker
- (3/82) TV commercials: Chrysler New Yorker, Cordoba and LeBaron automobiles.
- (10/28/86) Guest on the television news program "Live on Five".
- (2/10/69) Guest on the television program "The Morning Show".
- (12/19/67) Guest on the daytime program "Outrageous Opinions" hosted by Helen Gurley Brown.
- (8/11/70) Guest on the Los Angeles daytime program "Boutique" hosted by Steve Dunne and Stephanie Edwards.
- (6/17/70) Appeared in the documentary television program "Media: The Mexican-American Image" with Jesus Trevino. Also a condensed film of three "Ahora" shows.
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