- India's top spy Tiger and his love Zoya battle the dark world of intelligence and espionage that forbids its soldiers from loving the enemy.
- In the dark world of intelligence and espionage, all information is guarded in the name of national security. But some stories escape the fiercely-guarded classified files, stories that become legends. This is one such story, a story that shook the very foundation of this dark world. In a government employees' neighbourhood in New Delhi, lived a rugged, handsome and mysterious bachelor about whom his neighbours knew nothing. That was because he was India's top spy, an officer with the Research and Analysis Wing (RAW), India's external intelligence agency. This man was known even in official corridors as TIGER. Tiger is sent on a relatively easy and safe mission to Dublin, Ireland to observe a scientist of Indian origin who is suspected of sharing his research findings with the Pakistan defence establishment. Tiger attempts to meet the scientist but is not successful. He tries to befriend the scientist's part-time home caretaker Zoya. As Tiger gets closer to Zoya, he begins to discover his human side. For the first time in his life, Tiger falls in love. What follows is a tumultuous journey that Tiger and Zoya embark upon, battling the dark world of intelligence and espionage that forbids its soldiers to fall in love.—Official source
- An agent code-named "Tiger" (Salman Khan) - India's top spy and an officer of the Research and Analysis Wing (RAW) - is conducting a mission in northern Iraq. Tiger is forced to kill one of his own men who has defected to Pakistan's spy agency Inter-Services Intelligence (ISI). He subsequently kills many ISI agents in his escape.
Tiger returns to India and reports to his boss, Shenoy (Girish Karnad), in New Delhi. Shenoy advises Tiger to take some leave, but Tiger insists to be deployed on the next assignment, like he has been for the last 12 years. Tiger admits to Shenoy that he is a bit of a loner & has never had feelings for anyone in his life. Shenoy tells Tiger that he was also young once & had feelings for a girl. But he gave up the girl for his duty & regretted it ever since.
He is immediately sent on a mission to Dublin to observe a scientist of Indian origin, Professor Anwar Jamaal Kidwai (Roshan Seth), who teaches at Trinity College and is suspected of sharing his findings with the Pakistan defense establishment. Fellow RAW agent Gopi (Ranvir Shorey) accompanies Tiger on this mission. Tiger meets the scientist but fails to spend enough time for his observance, and instead begins to spend time with scientist's caretaker Zoya (Katrina Kaif), who is studying at a local dance academy. He tries to befriend Zoya to extract information, and he begins to discover his human side as he grows closer to her. Tiger is attacked and robbed at his residence by a person suspected to be an ISI agent.
Gopi repeatedly warns Tiger not to fall in love with Zoya, but he does. Before telling her his feelings during a visit to dance academy, Tiger discovers that Zoya is an ISI Agent and refuses to commit treason on Pakistan when he asks. Instead of killing Zoya, Tiger lets her go.
For a while Tiger takes a desk job in India & remembers his precious time with Zoya. Some time later, Tiger and Zoya meet again at a UN Foreign Minister's Meet in Istanbul when Zoya signals him to come using a cryptic message. They decide to leave everything for their love and fool their respective agencies by taken their flight to Brazil, having told their agencies that they are in Kazakhstan. Some years later, their agencies trace Zoya and Tiger to Cuba, and the ISI agents catch Zoya.
Tiger meets Gopi, who is searching for him for RAW, and having lied to Gopi that both Tiger and Zoya intend to return to India and cooperate with RAW, convinces Gopi to save Zoya from the ISI agents. Instead of returning to India, the pair escape aboard an airplane. Tiger calls Shenoy, who tells him that RAW will find both spies. Tiger tells Shenoy that they will return when Pakistan and India no longer need ISI and RAW. In the epilogue, several images of Tiger and Zoya in cities including Cape Town, Zurich and London are shown, where sightings of them have been reported.
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